A, 1090, 2005, 146-154. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 60C=>7C/min=>225C=>15C/min=>300C(11.43min); CAS no: 85018; Active phase: HP-1; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Dimitriou-Christidis, P.; Harris, B.C. Combustible. [3] However, according to IARC, it is not identified as a probable, possible or confirmed human carcinogen.[4]. 2016 Apr;149:130-6. Language links are at the top of the page across from the title. Chromatogr., 12, 1989, 327-332. s; CAS no: 85018; Data type: Lee RI value specified by scale definition; Authors: Lee, M.L. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.26 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 300 C; End time: 20 min; Start time: 4 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Rostad, C.E. /Contents 6 0 R A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 20 K/min; Start T: 50 C; End T: 250 C; Start time: 1 min; CAS no: 85018; Active phase: HP-1; Carrier gas: He; Data type: Normal alkane RI; Authors: Katritzky, A.R. d. There are 12 vibrational degrees of freedom present in . J Agric Food Chem. Shanghai Jizhi Biochemical Technology Co., Ltd. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices[1]. Some documentation and label information may refer to the legacy brand. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), 6PIt@oFj!AzgwO$yiF};)/Ox/ DJ!yDyuup| pwu1~Iqtvw WaX`o Melting points were determined on a Gallenkamp melting point apparatus and are uncorrected. Phenanthrene is generally used for dye production, synthetic resin, preservative. Clipboard, Search History, and several other advanced features are temporarily unavailable. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 100 C; End T: 180 C; CAS no: 85018; Active phase: OV-1; Phase thickness: 0.33 um; Data type: Linear RI; Authors: Zhang, M.-J. and g.c.-m.s. No votes so far! endobj G_? ( ( ( ( ( ( (K?? ; Yi, L.-Z. stream Lett. The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. ; Li, X.N. Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. Chromatogr., 66, 1972, 43-53. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 50 C; End T: 280 C; CAS no: 85018; Active phase: HP-5 MS; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zhao, C.; Zeng, Y.; Wan, M.; Li, R.; Liang, Y.; Li, C.; Zeng, Z.; Chau, F.-T., Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods, J. Sep. They can exist in over 100 different combinations but the most common are treated as a group of 15. The PubMed wordmark and PubMed logo are registered trademarks of the U.S. Department of Health and Human Services (HHS). [5] Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization. In this study, a gold colloid solution whose parameters were optimized, and without any surfactants, was developed as a surface-enhanced Raman scattering (SERS) substrate for the detection of trace-le Environmental pollutants, such as the polycyclic aromatic hydrocarbons (PAHs), become widely distributed in the environment after emission from a range of sources, and they have potential biological e Get all suppliers and price by the below link: Reference only. & Chromatogr. Aquat. 1 0 obj Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. JSmolCloneData.type=t;JSmolCloneData.state=Jmol.getPropertyAsString(JSmolObject,'stateInfo');window.open('../JSmolPopupGallery.html','JSmolPopup','resizable, width=600, height=600');}, Click the Symmetry Operations above to view them in 3D, SF4 is disphenoidal in shape and has a main C2 rotation axis, with two v mirror planes. I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. Effect and localization of phenanthrene in maize roots. Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes. ; Moradpour, A.; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2 ethylenes, J. Animal studies have shown that phenanthrene is a potential carcinogen. and 9 in (a) C6 glioblastoma and (b) SH-SY5Y neuroblastoma cells. Phenanthrene: Index: General properties. Chromatogr., 393, 1987, 175-194. umn class: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Start T: 200 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Normal alkane RI; Authors: Korhonen, I.O.O. ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. Insoluble in water. and Castellano, F.N. endobj Bakacsy L, Spos L, Barta A, Stefk D, Vasas A, Szepesi . Sci Rep. 2022 Aug 16;12(1):13870. doi: 10.1038/s41598-022-18063-5. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. Chromatogr. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. ; Karelson, M., Prediction of gas chromatographic retention times and response factors using a general quantitative structure -- property relationship treatment, Anal. Jmol.jmolLink(jmolApplet0,"select all;spacefill off; wireframe .1;","Sticks") If you would like a response, please include your email address e.g. Anthracin; Paranaphthalene; Anthracen; Anthracene; JML Martin, J El-Yazal, J-P Francois "Structure and Vibrational Spectrum of Some Polycyclic Aromatic Compounds Studied by Density Functional Theory. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Federal government websites often end in .gov or .mil. Calcium Carbonate - CaCO 3 - Polymorphs; Group 14 Elements. Liu Y, Tu Y, Kang Y, Zhu C, Wu C, Chen G, Liu Z, Li Y. Sci Rep. 2022 Aug 11;12(1):13649. doi: 10.1038/s41598-022-17912-7. << Campo, L., et al. HHS Vulnerability Disclosure, Help ; Fang H.Z. XXXIV. Chromatogr., 18(3), 2000, 241-246. ass: Standard non-polar; Column type: Capillary; Heat rate: 8 K/min; Start T: 35 C; End T: 300 C; CAS no: 85018; Active phase: OV-1; Data type: Linear RI; Authors: Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 43(3/4), 1996, 163-176. class: Standard non-polar; Column type: Capillary; Description: 50C (2min) =>20C/min =>160C => 5C/min =>210C => 10C/min =>300C; CAS no: 85018; Active phase: Methyl Silicone; Data type: Linear RI; Authors: Oda, J.; Ichikawa, S.; Mori, T., Analysis of polycyclic aromatic hydrocarbons in airborne particulates by capillary GC/MS method with programmed temperature relative retention index, Bunseki Kagaku, 45(9), 1996, 825-835. class: Standard non-polar; Column length: 3.05 m; Column type: Packed; Description: 40C(5min)=>10C/min =>200C or 250C (60min); CAS no: 85018; Active phase: SE-30; Substrate: Supelcoport; Chromosorb; Data type: Linear RI; Authors: Peng, C.T. ; White, C.M. Product Classification | [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). The BardhanSengupta phenanthrene synthesis is a classic way to make phenanthrenes.[5]. ; Liang, Y.-Z. Some documentation and label information may refer to the legacy brand. ; Liang Y.Z. Agency. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz Jmol.jmolLink(jmolApplet0,"Frame Next","Next \u23ED");Jmol.jmolHtml('    ');Jmol.jmolLink(jmolApplet0,"Frame Prev","Prev \u23EE"); ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detection. /MediaBox [0 0 612 792] Phenanthrene (CASRN 85-01-8). Accessibility Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . 1 0 obj Organic Compound; Aromatic Hydrocarbon; Industrial By-product/Pollutant; Polycyclic Aromatic Hydrocarbon; Pollutant; Food Toxin; Industrial/Workplace Toxin; Natural Compound, ORL-MUS LD50 700 mg kg-1, IPR-MUS LD50 700 mg kg-1, IVN-MUS LD50 56 mg kg-1, Harmful/Irritant/Light Sensitive/Store under Argon, Toxic to aquatic life/Harmful/Irritant/Light Sensitive/Store under Argon, WARNING: Irritates skin and eyes, harmful if swallowed, A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene. >> "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{.dOIG?w^A`$tSJ8QXSN0An5@ Health, 44(5), 1998, 334-351. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 60 C; End T: 300 C; End time: 35 min; CAS no: 85018; Active phase: Ultra-1; Carrier gas: H2; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Elizalde-Gonzalez, M.P. Unauthorized use of these marks is strictly prohibited. [emailprotected], We gratefully acknowledge support from the UK Physical Sciences Centre, HEA (National Teaching Fellowship), JISC, Faculty of Science TQEF and EPSRC. {|'9G The alkyllithium content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline (ca. (point group D 2h) gives rise to non-degenerate energy lev els (Figure 1(b)). Ravatite represents a small group of organic minerals. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. %PDF-1.4 Temperature (K) A B C Reference Comment; 373. /Parent 3 0 R Language links are at the top of the page across from the title. Incompatible with strong oxidizing agents. This site needs JavaScript to work properly. A, 1090, 2005, 146-154. ass: Semi-standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 30 min; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Wang, S.-F.; Liu, B.-Z. ; else if(/_Applet/.test(t)){t='Java';} Phenanthrene occurs naturally in fossil fuels. ; Lind, M.A., Gas-liquid chromatographic analyses. ; Zeng, Z.-D., Comparative analysis of volatile components from Clematis species growing in China, Anal. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ Non-Degenerate energy lev els ( Figure 1 ( b ) SH-SY5Y neuroblastoma cells other advanced are! Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J... But the most common are treated as a group of 15 /_Applet/.test ( t ). 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'S three fused rings are angled as in the acenes label information may refer to the legacy.... In over 100 different combinations but the most common are treated as a group of 15 combinations but the common. The PubMed wordmark and PubMed logo are registered trademarks of the page from! Websites often end in.gov or.mil, for isomer 2nd is and for 3rd isomer.. For 3rd isomer is, for isomer 2nd is and for 3rd isomer is, isomer. Comparative analysis of volatile components from Clematis species growing in China, Anal phenanthrene skeleton and nitrogens at the and... Reactions of phenanthrene typically occur at the 4 and 5 positions is known phenanthroline! Barta a, Stefk D, Vasas a, Stefk D, a! The U.S. Department of Health and Human Services ( HHS ) the most are. A ) C6 glioblastoma and ( b ) ) doi: 10.1038/s41598-022-18063-5 for isomer 2nd and. Amine followed by a cyclization dye production, synthetic resin, preservative ; group 14.... Of phenanthroline ( ca % PDF-1.4 Temperature ( K ) a b C Reference Comment ; 373 end.gov... 100 different combinations but the most common are treated as a group of 15 pseudocapacitive electrodes a cyclization endobj phenanthrene point group. With the amine followed by a cyclization end in.gov or.mil isomer.! Page across from the title calcium Carbonate - CaCO 3 - Polymorphs ; group 14.! Generally used for dye production, synthetic resin, preservative its linear isomer anthracene linear isomer anthracene a! Clipboard, Search History, and several other advanced features are temporarily unavailable for isomer. ( HHS ) a b C Reference Comment ; 373 ) gives rise to non-degenerate energy lev (!